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By surface
| Surface | Alessandro Caggiari | Kushaan Nath |
| Hard |
0 |
3 |
| Clay |
0 |
2 |
All meetings (5)
| Date | Tour | Tournament | Round | Surface | Winner |
Set 1 | Set 2 | Set 3 | Set 4 | Set 5 |
| 2010-05-24 |
WTA |
Roland Garros |
Round of 16 |
Clay |
Serena Williams |
2-6 |
2-6 |
|
|
|
| 2007-05-14 |
WTA |
Rome |
Round of 16 |
Clay |
Serena Williams |
3-6 |
3-6 |
|
|
|
| 2007-03-19 |
WTA |
Miami |
Semifinal |
Hard |
Serena Williams |
6-74 |
1-6 |
|
|
|
| 2007-01-15 |
WTA |
Australian Open |
Quarterfinal |
Hard |
Serena Williams |
6-3 |
2-6 |
6-8 |
|
|
| 2005-03-23 |
WTA |
Miami |
Round of 32 |
Hard |
Serena Williams |
3-6 |
3-6 |
|
|
|