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All meetings (8)
| Date | Tour | Tournament | Round | Surface | Winner |
Set 1 | Set 2 | Set 3 | Set 4 | Set 5 |
| 2018-08-13 |
WTA |
Cincinnati |
Round of 32 |
Hard |
Petra Kvitova |
3-6 |
6-2 |
3-6 |
|
|
| 2015-05-04 |
WTA |
Madrid |
Semifinal |
Clay |
Petra Kvitova |
2-6 |
3-6 |
|
|
|
| 2014-05-05 |
WTA |
Madrid |
Quarterfinal |
Clay |
Petra Kvitova |
DEF |
| 2013-10-21 |
WTA |
WTA Championships |
Round Robin |
Hard |
Serena Williams |
2-6 |
3-6 |
|
|
|
| 2013-02-11 |
WTA |
Doha |
Quarterfinal |
Hard |
Serena Williams |
6-3 |
3-6 |
5-7 |
|
|
| 2012-06-25 |
WTA |
Wimbledon |
Quarterfinal |
Grass |
Serena Williams |
3-6 |
5-7 |
|
|
|
| 2010-06-21 |
WTA |
Wimbledon |
Semifinal |
Grass |
Serena Williams |
6-75 |
2-6 |
|
|
|
| 2010-01-18 |
WTA |
Australian Open |
Round of 64 |
Hard |
Serena Williams |
2-6 |
1-6 |
|
|
|