By surface
| Surface | Valentina Castro | Martin Zimmermann |
|---|---|---|
| Clay | 2 | 0 |
All meetings (2)
| Date | Tour | Tournament | Round | Surface | Winner | Set 1 | Set 2 | Set 3 | Set 4 | Set 5 |
|---|---|---|---|---|---|---|---|---|---|---|
| 2006-04-21 | WTA | Fed Cup G1 RRA: CHI vs URU | Round Robin | Clay | Valentina Castro | 6-3 | 6-4 | |||
| 2004-04-19 | WTA | Fed Cup G1 RRB: CHI vs URU | Round Robin | Clay | Valentina Castro | 4-6 | 6-3 | 6-1 |