| # | Player | Pos | Season | Date | From | To | Type | Fee |
|---|---|---|---|---|---|---|---|---|
| 51 |  Julián Alvarez |
Attack - Centre-Forward | 24/25 | 2024-08-12 | Man City | Atlético Madrid | Transfer | €75.00m |
| 52 |  Matheus Cunha |
Attack - Second Striker | 25/26 | 2025-07-01 | Wolves | Man Utd | Transfer | €74.20m |
| 53 |  Alisson |
Goalkeeper | 18/19 | 2018-07-19 | AS Roma | Liverpool | Transfer | €72.50m |
| 54 |  Thomas Lemar |
Midfield - Attacking Midfield | 18/19 | 2018-07-01 | Monaco | Atlético Madrid | Transfer | €72.00m |
| 55 |  Rúben Dias |
Defender - Centre-Back | 20/21 | 2020-09-29 | Benfica | Man City | Transfer | €71.60m |
| 56 |  Casemiro |
Midfield - Defensive Midfield | 22/23 | 2022-08-22 | Real Madrid | Man Utd | Transfer | €70.65m |
| 57 |  Rodri |
Midfield - Defensive Midfield | 19/20 | 2019-07-04 | Atlético Madrid | Man City | Transfer | €70.00m |
| 58 |  Martín Zubimendi |
Midfield - Defensive Midfield | 25/26 | 2025-07-06 | Real Sociedad | Arsenal | Transfer | €70.00m |
| 59 |  Dominik Szoboszlai |
Midfield - Attacking Midfield | 23/24 | 2023-07-02 | RB Leipzig | Liverpool | Transfer | €70.00m |
| 60 |  Luis Díaz |
Attack - Left Winger | 25/26 | 2025-07-30 | Liverpool | Bayern Munich | Transfer | €70.00m |
| 61 |  Khvicha Kvaratskhelia |
Attack - Left Winger | 24/25 | 2025-01-17 | Napoli | Paris SG | Transfer | €70.00m |
| 62 |  Mykhaylo Mudryk |
Attack - Left Winger | 22/23 | 2023-01-15 | Shakhtar D. | Chelsea | Transfer | €70.00m |
| 63 |  Zlatan Ibrahimović |
Attack - Centre-Forward | 09/10 | 2009-07-27 | Inter | Barcelona | Transfer | €69.50m |
| 64 |  Eberechi Eze |
Midfield - Attacking Midfield | 25/26 | 2025-08-23 | Crystal Palace | Arsenal | Transfer | €69.30m |
| 65 |  Mateo Retegui |
Attack - Centre-Forward | 25/26 | 2025-07-21 | Atalanta BC | Al-Qadsiah | Transfer | €68.25m |
| 66 |  Achraf Hakimi |
Defender - Right-Back | 21/22 | 2021-07-06 | Inter | Paris SG | Transfer | €68.00m |
| 67 |  Riyad Mahrez |
Attack - Right Winger | 18/19 | 2018-07-10 | Leicester | Man City | Transfer | €67.80m |
| 68 |  Mason Mount |
Midfield - Attacking Midfield | 23/24 | 2023-07-05 | Chelsea | Man Utd | Transfer | €67.70m |
| 69 |  Kaká |
Midfield - Attacking Midfield | 09/10 | 2009-07-01 | AC Milan | Real Madrid | Transfer | €67.00m |
| 70 |  Álvaro Morata |
Attack - Centre-Forward | 17/18 | 2017-07-21 | Real Madrid | Chelsea | Transfer | €66.00m |
| 71 |  Viktor Gyökeres |
Attack - Centre-Forward | 25/26 | 2025-07-26 | Sporting CP | Arsenal | Transfer | €65.80m |
| 72 |  Marc Cucurella |
Defender - Left-Back | 22/23 | 2022-08-05 | Brighton | Chelsea | Transfer | €65.30m |
| 73 |  Aymeric Laporte |
Defender - Centre-Back | 17/18 | 2018-01-30 | Athletic | Man City | Transfer | €65.00m |
| 74 |  João Cancelo |
Defender - Right-Back | 19/20 | 2019-08-07 | Juventus | Man City | Transfer | €65.00m |
| 75 |  Bruno Fernandes |
Midfield - Attacking Midfield | 19/20 | 2020-01-29 | Sporting CP | Man Utd | Transfer | €65.00m |
| 76 |  Gonçalo Ramos |
Attack - Centre-Forward | 23/24 | 2024-01-01 | Benfica | Paris SG | Transfer | €65.00m |
| 77 |  Xavi Simons |
Midfield - Attacking Midfield | 25/26 | 2025-08-29 | RB Leipzig | Tottenham | Transfer | €65.00m |
| 78 |  Edinson Cavani |
Attack - Centre-Forward | 13/14 | 2013-07-16 | Napoli | Paris SG | Transfer | €64.50m |
| 79 |  Dominic Solanke |
Attack - Centre-Forward | 24/25 | 2024-08-10 | Bournemouth | Tottenham | Transfer | €64.30m |
| 80 |  Christian Pulisic |
Attack - Right Winger | 18/19 | 2019-01-02 | Bor. Dortmund | Chelsea | Transfer | €64.00m |
| 81 |  Mohammed Kudus |
Attack - Right Winger | 25/26 | 2025-07-10 | West Ham | Tottenham | Transfer | €63.80m |
| 82 |  Pierre-Emerick Aubameyang |
Attack - Centre-Forward | 17/18 | 2018-01-31 | Bor. Dortmund | Arsenal | Transfer | €63.75m |
| 83 |  Raheem Sterling |
Attack - Right Winger | 15/16 | 2015-07-14 | Liverpool | Man City | Transfer | €63.70m |
| 84 |  João Pedro |
Attack - Centre-Forward | 25/26 | 2025-07-02 | Brighton | Chelsea | Transfer | €63.70m |
| 85 |  Luka Jović |
Attack - Centre-Forward | 19/20 | 2019-07-02 | E. Frankfurt | Real Madrid | Transfer | €63.00m |
| 86 |  Ilya Zabarnyi |
Defender - Centre-Back | 25/26 | 2025-08-12 | Bournemouth | Paris SG | Transfer | €63.00m |
| 87 |  Dean Huijsen |
Defender - Centre-Back | 25/26 | 2025-06-01 | Bournemouth | Real Madrid | Transfer | €62.50m |
| 88 |  Roméo Lavia |
Midfield - Defensive Midfield | 23/24 | 2023-08-18 | Southampton | Chelsea | Transfer | €62.10m |
| 89 |  Tanguy Ndombélé |
Midfield - Central Midfield | 19/20 | 2019-07-02 | Olympique Lyon | Tottenham | Transfer | €62.00m |
| 90 |  Matheus Nunes |
Midfield - Central Midfield | 23/24 | 2023-09-01 | Wolves | Man City | Transfer | €62.00m |
| 91 |  Leny Yoro |
Defender - Centre-Back | 24/25 | 2024-07-18 | LOSC Lille | Man Utd | Transfer | €62.00m |
| 92 |  Anthony Elanga |
Attack - Right Winger | 25/26 | 2025-07-11 | Forest | Newcastle | Transfer | €61.40m |
| 93 |  Luís Figo |
Attack - Right Winger | 00/01 | 2000-07-24 | Barcelona | Real Madrid | Transfer | €60.00m |
| 94 |  Miralem Pjanić |
Midfield - Central Midfield | 20/21 | 2020-09-01 | Juventus | Barcelona | Transfer | €60.00m |
| 95 |  Diego Costa |
Attack - Centre-Forward | 17/18 | 2018-01-01 | Chelsea | Atlético Madrid | Transfer | €60.00m |
| 96 |  Oscar |
Midfield - Attacking Midfield | 16/17 | 2017-01-01 | Chelsea | SH SIPG | Transfer | €60.00m |
| 97 |  Anthony Martial |
Attack - Centre-Forward | 15/16 | 2015-09-01 | Monaco | Man Utd | Transfer | €60.00m |
| 98 |  Otávio |
Midfield - Attacking Midfield | 23/24 | 2023-08-22 | FC Porto | Al-Nassr | Transfer | €60.00m |
| 99 |  Naby Keïta |
Midfield - Central Midfield | 18/19 | 2018-07-01 | RB Leipzig | Liverpool | Transfer | €60.00m |
| 100 |  Malcom |
Midfield - Attacking Midfield | 23/24 | 2023-07-26 | Zenit S-Pb | Al-Hilal | Transfer | €60.00m |
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