| # | Player | Position | Citizenship | Club | Born | Value |
|---|---|---|---|---|---|---|
| 1 |  Sylvain Distin | Defender - Centre-Back | France Guadeloupe | Retired | 1977 | - |
| 2 |  Kim Madsen | Defender - Centre-Back | Denmark | Retired | 1978 | - |
| 3 |  Peter Lérant | Defender - Centre-Back | Slovakia | Retired | 1977 | - |
| 4 |  Lúcio | Defender - Centre-Back | Brazil | Retired | 1978 | - |
| 5 |  Kakhaber Kaladze | Defender - Centre-Back | Georgia | Retired | 1978 | - |
| 6 |  Samuel Kuffour | Defender - Centre-Back | Ghana Germany | Retired | 1976 | - |
| 7 |  William Gallas | Defender - Centre-Back | France Guadeloupe | Retired | 1977 | - |
| 8 |  Rui Marques | Defender - Centre-Back | Angola Portugal | Retired | 1977 | - |
| 9 |  Metin Aslan | Defender - Centre-Back | Türkiye Austria | Retired | 1978 | - |
| 10 |  Alexander Maul | Defender - Centre-Back | Germany | Retired | 1976 | - |
| 11 |  Jan Schanda | Defender - Centre-Back | Germany | Retired | 1977 | - |
| 12 |  Dame Diouf | Defender - Centre-Back | Senegal | Retired | 1978 | - |
| 13 |  Jae-won Sim | Defender - Centre-Back | Korea, South | Retired | 1977 | - |
| 14 |  Boris Smiljanic | Defender - Centre-Back | Switzerland Croatia | Retired | 1976 | - |
| 15 |  Moses Sichone | Defender - Centre-Back | Zambia Germany | Retired | 1977 | - |
| 16 |  Christian Kritzer | Defender - Centre-Back | Germany | Retired | 1977 | - |
| 17 |  Deniz Barış | Defender - Centre-Back | Türkiye Germany | Retired | 1977 | - |
| 18 |  Josip Simunic | Defender - Centre-Back | Croatia Australia | Retired | 1978 | - |
| 19 |  Volker Oppitz | Defender - Centre-Back | Germany | Retired | 1978 | - |
| 20 |  Sascha Laschet | Defender - Centre-Back | Austria | Retired | 1977 | - |
| 21 |  Arthur Matlik | Defender - Centre-Back | Germany Poland | Retired | 1977 | - |
| 22 |  Hayden Foxe | Defender - Centre-Back | Australia | Retired | 1977 | - |
| 23 |  Olof Mellberg | Defender - Centre-Back | Sweden | Retired | 1977 | - |
| 24 |  Rigobert Song | Defender - Centre-Back | Cameroon France | Retired | 1976 | - |
| 25 |  Markus Ehrhard | Defender - Centre-Back | Germany | Retired | 1976 | - |
| 26 |  Thomas Cichon | Defender - Centre-Back | Germany Poland | Retired | 1976 | - |
| 27 |  Darren Purse | Defender - Centre-Back | England | Retired | 1977 | - |
| 28 |  Jens Langeneke | Defender - Centre-Back | Germany | Retired | 1977 | - |
| 29 |  Pascal Castillo | Defender - Centre-Back | Switzerland | Retired | 1976 | - |
| 30 |  Fernando Meira | Defender - Centre-Back | Portugal | Retired | 1978 | - |