| # | Player | Position | Citizenship | Club | Born | Value |
|---|---|---|---|---|---|---|
| 1 |  César Azpilicueta | Defender - Centre-Back | Spain | Sevilla FC | 1989 | €1.5m |
| 2 |  Craig Dawson | Defender - Centre-Back | England | Without Club | 1990 | €1.5m |
| 3 |  Chris Smalling | Defender - Centre-Back | England Jamaica | Al-Fayha FC | 1989 | €1.5m |
| 4 |  Willy Boly | Defender - Centre-Back | Cote d'Ivoire France | Nottingham Forest | 1991 | €1.5m |
| 5 |  Rafael Tolói | Defender - Centre-Back | Italy Brazil | São Paulo Futebol Clube | 1990 | €1.4m |
| 6 |  Ahmed Hegazy | Defender - Centre-Back | Egypt | NEOM SC | 1991 | €1.2m |
| 7 |  Romain Saïss | Defender - Centre-Back | Morocco France | Al-Sadd SC | 1990 | €1.8m |
| 8 |  Nacho Fernández | Defender - Centre-Back | Spain | Al-Qadsiah FC | 1990 | €2.0m |
| 9 |  Gabriel Paulista | Defender - Centre-Back | Brazil Spain | Besiktas JK | 1990 | €1.0m |
| 10 |  Marc Bartra | Defender - Centre-Back | Spain | Real Betis Balompié | 1991 | €1.0m |
| 11 |  Grégory Mertens | Defender - Centre-Back | Belgium | --- | 1991 | €1.0m |
| 12 |  David López | Defender - Centre-Back | Spain | Girona FC | 1989 | €1.0m |
| 13 |  Stefan Savic | Defender - Centre-Back | Montenegro Serbia | Trabzonspor | 1991 | €0.9m |
| 14 |  Sebastián Coates | Defender - Centre-Back | Uruguay Spain | Club Nacional | 1990 | €0.8m |
| 15 |  Álvaro González | Defender - Centre-Back | Spain | CD Tenerife | 1990 | €0.8m |
| 16 |  Pontus Jansson | Defender - Centre-Back | Sweden | Malmö FF | 1991 | €0.8m |
| 17 |  Domagoj Vida | Defender - Centre-Back | Croatia | AEK Athens | 1989 | €0.7m |
| 18 |  José Luis Palomino | Defender - Centre-Back | Argentina Bulgaria | CA Talleres | 1990 | €0.7m |
| 19 |  Christian Kabasele | Defender - Centre-Back | Belgium DR Congo | Udinese Calcio | 1991 | €0.7m |
| 20 |  Luca Caldirola | Defender - Centre-Back | Italy | Without Club | 1991 | €0.7m |
| 21 |  Ben Mee | Defender - Centre-Back | England | Sheffield United | 1989 | €0.7m |
| 22 |  Stefan Mitrovic | Defender - Centre-Back | Serbia | KAA Gent | 1990 | €0.7m |
| 23 |  Dejan Lovren | Defender - Centre-Back | Croatia | PAOK Thessaloniki | 1989 | €0.6m |
| 24 |  Hugo Nervo | Defender - Centre-Back | Argentina | CA Huracán | 1991 | €0.6m |
| 25 |  Pedro Bigas | Defender - Centre-Back | Spain | Elche CF | 1990 | €0.5m |
| 26 |  Jeong-ho Hong | Defender - Centre-Back | Korea, South | Jeonbuk Hyundai Motors | 1989 | €0.5m |
| 27 |  Armando Izzo | Defender - Centre-Back | Italy | AC Monza | 1992 | €1.5m |
| 28 |  André Ramalho | Defender - Centre-Back | Brazil Italy | Sport Club Corinthians Paulista | 1992 | €1.5m |
| 29 |  Juan Jesus | Defender - Centre-Back | Brazil Italy | SSC Napoli | 1991 | €1.5m |
| 30 |  Jeffrey Gouweleeuw | Defender - Centre-Back | Netherlands | FC Augsburg | 1991 | €1.5m |