| # | Player | Position | Citizenship | Club | Born | Value |
|---|---|---|---|---|---|---|
| 1 |  Rico Henry | Defender - Left-Back | England Jamaica | Brentford FC | 1997 | €15.0m |
| 2 |  Caio Henrique | Defender - Left-Back | Brazil Spain | AS Monaco | 1997 | €15.0m |
| 3 |  Joakim Mæhle | Defender - Left-Back | Denmark | VfL Wolfsburg | 1997 | €14.0m |
| 4 |  Konstantinos Tsimikas | Defender - Left-Back | Greece | AS Roma | 1996 | €18.0m |
| 5 |  Oleksandr Zinchenko | Defender - Left-Back | Ukraine | Nottingham Forest | 1996 | €20.0m |
| 6 |  Mathías Olivera | Defender - Left-Back | Uruguay Spain | SSC Napoli | 1997 | €20.0m |
| 7 |  Angeliño | Defender - Left-Back | Spain | AS Roma | 1997 | €20.0m |
| 8 |  Maximilian Mittelstädt | Defender - Left-Back | Germany | VfB Stuttgart | 1997 | €20.0m |
| 9 |  Kieran Tierney | Defender - Left-Back | Scotland Isle of Man | Celtic FC | 1997 | €9.0m |
| 10 |  Junior Firpo | Defender - Left-Back | Dominican Republic Spain | Real Betis Balompié | 1996 | €8.0m |
| 11 |  Guilherme Arana | Defender - Left-Back | Brazil | Clube Atlético Mineiro | 1997 | €8.0m |
| 12 |  Sergio Akieme | Defender - Left-Back | Spain Equatorial Guinea | Stade Reims | 1997 | €7.0m |
| 13 |  Gijs Smal | Defender - Left-Back | Netherlands | Feyenoord Rotterdam | 1997 | €7.0m |
| 14 |  Aarón Martín | Defender - Left-Back | Spain | Genoa CFC | 1997 | €6.5m |
| 15 |  Greg Taylor | Defender - Left-Back | Scotland | PAOK Thessaloniki | 1997 | €6.0m |
| 16 |  Ayrton Lucas | Defender - Left-Back | Brazil | CR Flamengo | 1997 | €6.0m |
| 17 |  Sergio Reguilón | Defender - Left-Back | Spain | Without Club | 1996 | €6.0m |
| 18 |  Juninho Capixaba | Defender - Left-Back | Brazil | Red Bull Bragantino | 1997 | €6.0m |
| 19 |  Kai Wagner | Defender - Left-Back | Germany | Philadelphia Union | 1997 | €5.0m |
| 20 |  Lucas Hernández | Defender - Left-Back | France Spain | Paris Saint-Germain | 1996 | €25.0m |
| 21 |  Ulisses Garcia | Defender - Left-Back | Switzerland Cape Verde | Olympique Marseille | 1996 | €5.0m |
| 22 |  Matías Viña | Defender - Left-Back | Uruguay Italy | CR Flamengo | 1997 | €5.0m |
| 23 |  Romain Perraud | Defender - Left-Back | France | LOSC Lille | 1997 | €5.0m |
| 24 |  Antonee Robinson | Defender - Left-Back | United States England | Fulham FC | 1997 | €35.0m |
| 25 |  Joaquín Piquerez | Defender - Left-Back | Uruguay Italy | Sociedade Esportiva Palmeiras | 1998 | €15.0m |
| 26 |  Ferland Mendy | Defender - Left-Back | France Senegal | Real Madrid | 1995 | €14.0m |
| 27 |  Renan Lodi | Defender - Left-Back | Brazil Italy | Al-Hilal SFC | 1998 | €13.0m |
| 28 |  Luke Shaw | Defender - Left-Back | England | Manchester United | 1995 | €12.0m |
| 29 |  David Raum | Defender - Left-Back | Germany | RB Leipzig | 1998 | €20.0m |
| 30 |  José Gayà | Defender - Left-Back | Spain | Valencia CF | 1995 | €9.0m |