| # | Player | Position | Citizenship | Club | Born | Value |
|---|---|---|---|---|---|---|
| 1 |  Mathías Olivera | Defender - Left-Back | Uruguay Spain | SSC Napoli | 1997 | €20.0m |
| 2 |  Caio Henrique | Defender - Left-Back | Brazil Spain | AS Monaco | 1997 | €15.0m |
| 3 |  Joaquín Piquerez | Defender - Left-Back | Uruguay Italy | Sociedade Esportiva Palmeiras | 1998 | €15.0m |
| 4 |  Rico Henry | Defender - Left-Back | England Jamaica | Brentford FC | 1997 | €15.0m |
| 5 |  Joakim Mæhle | Defender - Left-Back | Denmark | VfL Wolfsburg | 1997 | €14.0m |
| 6 |  Carlos Augusto | Defender - Left-Back | Brazil Italy | Inter Milan | 1999 | €26.0m |
| 7 |  Renan Lodi | Defender - Left-Back | Brazil Italy | Al-Hilal SFC | 1998 | €13.0m |
| 8 |  Pervis Estupiñán | Defender - Left-Back | Ecuador Spain | AC Milan | 1998 | €30.0m |
| 9 |  Kieran Tierney | Defender - Left-Back | Scotland Isle of Man | Celtic FC | 1997 | €9.0m |
| 10 |  Adrià Pedrosa | Defender - Left-Back | Spain | Elche CF | 1998 | €7.0m |
| 11 |  Gijs Smal | Defender - Left-Back | Netherlands | Feyenoord Rotterdam | 1997 | €7.0m |
| 12 |  Sergio Akieme | Defender - Left-Back | Spain Equatorial Guinea | Stade Reims | 1997 | €7.0m |
| 13 |  Ayrton Lucas | Defender - Left-Back | Brazil | CR Flamengo | 1997 | €6.0m |
| 14 |  Greg Taylor | Defender - Left-Back | Scotland | PAOK Thessaloniki | 1997 | €6.0m |
| 15 |  Juninho Capixaba | Defender - Left-Back | Brazil | Red Bull Bragantino | 1997 | €6.0m |
| 16 |  Marc Cucurella | Defender - Left-Back | Spain | Chelsea FC | 1998 | €35.0m |
| 17 |  Antonee Robinson | Defender - Left-Back | United States England | Fulham FC | 1997 | €35.0m |
| 18 |  Federico Dimarco | Defender - Left-Back | Italy | Inter Milan | 1997 | €50.0m |
| 19 |  Angeliño | Defender - Left-Back | Spain | AS Roma | 1997 | €20.0m |
| 20 |  Maximilian Mittelstädt | Defender - Left-Back | Germany | VfB Stuttgart | 1997 | €20.0m |
| 21 |  Oleksandr Zinchenko | Defender - Left-Back | Ukraine | Nottingham Forest | 1996 | €20.0m |
| 22 |  Fran García | Defender - Left-Back | Spain | Real Madrid | 1999 | €18.0m |
| 23 |  Konstantinos Tsimikas | Defender - Left-Back | Greece | AS Roma | 1996 | €18.0m |
| 24 |  Leif Davis | Defender - Left-Back | England | Ipswich Town | 1999 | €22.0m |
| 25 |  Tyrick Mitchell | Defender - Left-Back | England Jamaica | Crystal Palace | 1999 | €25.0m |
| 26 |  Nuno Tavares | Defender - Left-Back | Portugal Cape Verde | SS Lazio | 2000 | €25.0m |
| 27 |  Juan Miranda | Defender - Left-Back | Spain | Bologna FC 1909 | 2000 | €15.0m |
| 28 |  Ferdi Kadıoğlu | Defender - Left-Back | Türkiye Netherlands | Brighton & Hove Albion | 1999 | €25.0m |
| 29 |  Ben Chilwell | Defender - Left-Back | England New Zealand | RC Strasbourg Alsace | 1996 | €15.0m |
| 30 |  Francisco Moura | Defender - Left-Back | Portugal | FC Porto | 1999 | €15.0m |