| # | Player | Position | Citizenship | Club | Born | Value |
|---|---|---|---|---|---|---|
| 1 |  César Azpilicueta | Defender - Centre-Back | Spain | Sevilla FC | 1989 | €1.5m |
| 2 |  Chris Smalling | Defender - Centre-Back | England Jamaica | Al-Fayha FC | 1989 | €1.5m |
| 3 |  Nicolás Otamendi | Defender - Centre-Back | Argentina | SL Benfica | 1988 | €1.0m |
| 4 |  Francesco Acerbi | Defender - Centre-Back | Italy | Inter Milan | 1988 | €3.0m |
| 5 |  David López | Defender - Centre-Back | Spain | Girona FC | 1989 | €1.0m |
| 6 |  Javi Martínez | Defender - Centre-Back | Spain | Al-Bidda SC | 1988 | €0.8m |
| 7 |  Álvaro González | Defender - Centre-Back | Spain | CD Tenerife | 1990 | €0.8m |
| 8 |  Ben Mee | Defender - Centre-Back | England | Sheffield United | 1989 | €0.7m |
| 9 |  Domagoj Vida | Defender - Centre-Back | Croatia | AEK Athens | 1989 | €0.7m |
| 10 |  José Luis Palomino | Defender - Centre-Back | Argentina Bulgaria | CA Talleres | 1990 | €0.7m |
| 11 |  Dejan Lovren | Defender - Centre-Back | Croatia | PAOK Thessaloniki | 1989 | €0.6m |
| 12 |  Nacho Fernández | Defender - Centre-Back | Spain | Al-Qadsiah FC | 1990 | €2.0m |
| 13 |  Romain Saïss | Defender - Centre-Back | Morocco France | Al-Sadd SC | 1990 | €1.8m |
| 14 |  Craig Dawson | Defender - Centre-Back | England | Without Club | 1990 | €1.5m |
| 15 |  Daley Blind | Defender - Centre-Back | Netherlands | Girona FC | 1990 | €1.5m |
| 16 |  Rafael Tolói | Defender - Centre-Back | Italy Brazil | São Paulo Futebol Clube | 1990 | €1.4m |
| 17 |  Gabriel Paulista | Defender - Centre-Back | Brazil Spain | Besiktas JK | 1990 | €1.0m |
| 18 |  Stefan Savic | Defender - Centre-Back | Montenegro Serbia | Trabzonspor | 1991 | €0.9m |
| 19 |  Sebastián Coates | Defender - Centre-Back | Uruguay Spain | Club Nacional | 1990 | €0.8m |
| 20 |  Stefan Mitrovic | Defender - Centre-Back | Serbia | KAA Gent | 1990 | €0.7m |
| 21 |  Hugo Nervo | Defender - Centre-Back | Argentina | CA Huracán | 1991 | €0.6m |
| 22 |  Fabián Balbuena | Defender - Centre-Back | Paraguay | Grêmio Foot-Ball Porto Alegrense | 1991 | €2.0m |
| 23 |  Christian Burgess | Defender - Centre-Back | England | Union Saint-Gilloise | 1991 | €2.2m |
| 24 |  Dakonam Djené | Defender - Centre-Back | Togo | Getafe CF | 1991 | €1.8m |
| 25 |  Antonio Raíllo | Defender - Centre-Back | Spain | RCD Mallorca | 1991 | €1.8m |
| 26 |  Germán Pezzella | Defender - Centre-Back | Argentina Italy | CA River Plate | 1991 | €1.8m |
| 27 |  Jeffrey Gouweleeuw | Defender - Centre-Back | Netherlands | FC Augsburg | 1991 | €1.5m |
| 28 |  Willy Boly | Defender - Centre-Back | Cote d'Ivoire France | Nottingham Forest | 1991 | €1.5m |
| 29 |  Florian Lejeune | Defender - Centre-Back | France | Rayo Vallecano | 1991 | €2.5m |
| 30 |  Juan Jesus | Defender - Centre-Back | Brazil Italy | SSC Napoli | 1991 | €1.5m |