| # | Player | Position | Citizenship | Club | Born | Value |
|---|---|---|---|---|---|---|
| 1 |  Ruslan Litvinov | Defender - Centre-Back | Russia | Spartak Moscow | 2001 | €5.0m |
| 2 |  Adrian Leon Barisic | Defender - Centre-Back | Bosnia-Herzegovina Croatia | FC Basel 1893 | 2001 | €5.0m |
| 3 |  Micael | Defender - Centre-Back | Brazil | Sociedade Esportiva Palmeiras | 2000 | €5.0m |
| 4 |  Sinaly Diomandé | Defender - Centre-Back | Cote d'Ivoire | AJ Auxerre | 2001 | €5.0m |
| 5 |  Clément Akpa | Defender - Centre-Back | Cote d'Ivoire France | AJ Auxerre | 2001 | €5.0m |
| 6 |  Ramon Hendriks | Defender - Centre-Back | Netherlands | VfB Stuttgart | 2001 | €5.0m |
| 7 |  David Affengruber | Defender - Centre-Back | Austria | Elche CF | 2001 | €5.0m |
| 8 |  Arthur Chaves | Defender - Centre-Back | Brazil | TSG 1899 Hoffenheim | 2001 | €5.0m |
| 9 |  Kamil Piatkowski | Defender - Centre-Back | Poland | Legia Warszawa | 2000 | €4.5m |
| 10 |  Becir Omeragic | Defender - Centre-Back | Switzerland Bosnia-Herzegovina | Montpellier HSC | 2002 | €4.5m |
| 11 |  Arseniy Batagov | Defender - Centre-Back | Ukraine | Trabzonspor | 2002 | €4.5m |
| 12 |  João Marcelo | Defender - Centre-Back | Brazil | Cruzeiro Esporte Clube | 2000 | €5.5m |
| 13 |  Ibrahima Bamba | Defender - Centre-Back | Italy Cote d'Ivoire | Al-Duhail SC | 2002 | €5.5m |
| 14 |  David Zima | Defender - Centre-Back | Czech Republic | SK Slavia Prague | 2000 | €5.5m |
| 15 |  Emirhan Topçu | Defender - Centre-Back | Türkiye | Besiktas JK | 2000 | €5.5m |
| 16 |  Teden Mengi | Defender - Centre-Back | England Angola | Luton Town | 2002 | €5.5m |
| 17 |  Mattia Viti | Defender - Centre-Back | Italy | ACF Fiorentina | 2002 | €5.5m |
| 18 |  Gabriel Xavier | Defender - Centre-Back | Brazil | Esporte Clube Bahia | 2001 | €4.0m |
| 19 |  David Nemeth | Defender - Centre-Back | Austria | FC St. Pauli | 2001 | €4.0m |
| 20 |  Bamo Meïté | Defender - Centre-Back | Cote d'Ivoire France | FC Lorient | 2001 | €4.0m |
| 21 |  Raúl Torrente | Defender - Centre-Back | Spain | GNK Dinamo Zagreb | 2001 | €4.0m |
| 22 |  Federico Bonini | Defender - Centre-Back | Italy | UD Almería | 2001 | €4.0m |
| 23 |  Christoph Klarer | Defender - Centre-Back | Austria | Birmingham City | 2000 | €4.0m |
| 24 |  Jorge Herrando | Defender - Centre-Back | Spain | CA Osasuna | 2001 | €4.0m |
| 25 |  Abdoulaye Ndiaye | Defender - Centre-Back | Senegal | Parma Calcio 1913 | 2002 | €4.0m |
| 26 |  Jamil Siebert | Defender - Centre-Back | Germany | US Lecce | 2002 | €4.0m |
| 27 |  Lorenzo Pirola | Defender - Centre-Back | Italy | Olympiacos Piraeus | 2002 | €6.0m |
| 28 |  Jon Pacheco | Defender - Centre-Back | Spain | Deportivo Alavés | 2001 | €6.0m |
| 29 |  Thomas Kristensen | Defender - Centre-Back | Denmark | Udinese Calcio | 2002 | €6.0m |
| 30 |  Christopher Wooh | Defender - Centre-Back | Cameroon France | Spartak Moscow | 2001 | €6.0m |