| # | Player | Position | Citizenship | Club | Born | Value |
|---|---|---|---|---|---|---|
| 1 |  Mats Hummels | Defender - Centre-Back | Germany | Retired | 1988 | — |
| 2 |  Simone Grippo | Defender - Centre-Back | Switzerland Italy | Retired | 1988 | — |
| 3 |  Ricardo Chará | Defender - Centre-Back | Colombia | Unknown | 1990 | — |
| 4 |  Frédéric Frans | Defender - Centre-Back | Belgium | Retired | 1989 | — |
| 5 |  Nihat Ocak | Defender - Centre-Back | Türkiye | Unknown | 1989 | — |
| 6 |  Ismo Vorstermans | Defender - Centre-Back | Netherlands | Retired | 1989 | — |
| 7 |  Toby Alderweireld | Defender - Centre-Back | Belgium | Retired | 1989 | — |
| 8 |  Arkadiusz Golab | Defender - Centre-Back | Poland | Unknown | 1989 | — |
| 9 |  Jordy Buijs | Defender - Centre-Back | Netherlands | Retired | 1988 | — |
| 10 |  Cédric Mongongu | Defender - Centre-Back | DR Congo France | Retired | 1989 | — |
| 11 |  Christopher Schorch | Defender - Centre-Back | Germany | Retired | 1989 | — |
| 12 |  Patrick O'Connor | Defender - Centre-Back | Ireland England | Unknown | 1990 | — |
| 13 |  Florian Jungwirth | Defender - Centre-Back | Germany | Retired | 1989 | — |
| 14 |  Aykut Demir | Defender - Centre-Back | Türkiye Netherlands | Retired | 1988 | — |
| 15 |  Sergey Morozov | Defender - Centre-Back | Russia | Retired | 1989 | — |
| 16 |  Mateo Musacchio | Defender - Centre-Back | Argentina Italy | Retired | 1990 | — |
| 17 |  Kevin Pezzoni | Defender - Centre-Back | Germany Italy | Retired | 1989 | — |
| 18 |  Guillaume Rubulotta | Defender - Centre-Back | France | Unknown | 1989 | — |
| 19 |  Gaetano Calà | Defender - Centre-Back | Italy | Unknown | 1989 | — |
| 20 |  Adam Marciniak | Defender - Centre-Back | Poland | Retired | 1988 | — |
| 21 |  Adilson | Defender - Centre-Back | Cape Verde Portugal | Unknown | 1988 | — |
| 22 |  Slobodan Rajković | Defender - Centre-Back | Serbia | Retired | 1989 | — |
| 23 |  Fidel Vázquez | Defender - Centre-Back | Mexico | Unknown | 1989 | — |
| 24 |  Neven Subotic | Defender - Centre-Back | Germany Serbia | Retired | 1988 | — |
| 25 |  Harry Worley | Defender - Centre-Back | England | Retired | 1988 | — |
| 26 |  Felix Schiller | Defender - Centre-Back | Germany | Retired | 1989 | — |
| 27 |  Sascha Kotysch | Defender - Centre-Back | Germany Belgium | Retired | 1988 | — |
| 28 |  Claus Gold | Defender - Centre-Back | Argentina | Unknown | 1990 | — |
| 29 |  Dele Adeleye | Defender - Centre-Back | Nigeria | Retired | 1988 | — |
| 30 |  Maciej Wilusz | Defender - Centre-Back | Poland | Retired | 1988 | — |